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Synthesis and Properties of Tetrabutylammonium Octaiododirhenate( III ),[( n ‐C 4 H 9 ) 4 N] 2 [Re 2 I 8 ]
Author(s) -
Preetz Wilhelm,
Rudzik Lutz
Publication year - 1979
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197901501
Subject(s) - ion , chemistry , iodine , inorganic chemistry , crystallography , mineralogy , organic chemistry
Salts of the anion [Re 2 I 8 ] 2− , containing a ReRe quadruple bond , have hitherto defied preparation. However, they are accessible by reaction in nonaqueous solution. The HI used should be free from water and iodine (XCL, Br).