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Structure and Bonding in Cyclic Sulfur‐Nitrogen Compounds
Author(s) -
Roesky Herbert W.
Publication year - 1979
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197900913
Subject(s) - sulfur , delocalized electron , nitrogen , chemistry , electron delocalization , coordination number , polymer chemistry , inorganic chemistry , crystallography , organic chemistry , ion
Abstract The coordination number of sulfur is used in this review as a classification principle; cyclic sulfur‐nitrogen compounds in which the sulfur is di‐, tri‐, and tetracoordinated are discussed. Compounds with sulfur (and nitrogen) of coordination number 2 are electron‐rich combinations of elements whose π‐electrons are extensively delocalized. A correlation between the coordination number and the bond length can be observed in certain compounds containing tri‐ and tetracoordinated sulfur.

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