Preparation of a New Series of Trinuclear Metallophthalocyanines and ‐porphyrins | Zendy

Kato Shinzi | Zendy; Noda Ippei | Zendy; Mizuta Masateru | Zendy; Itoh Yuji | Zendy

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Preparation of a New Series of Trinuclear Metallophthalocyanines and ‐porphyrins

Author(s) -

Kato Shinzi,

Noda Ippei,

Mizuta Masateru,

Itoh Yuji

Publication year - 1979

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.197900821

Subject(s) - rhenium , carbyne , carbide , tetraphenylporphyrin , tin , chemistry , crystallography , atom (system on chip) , porphyrin , inorganic chemistry , photochemistry , catalysis , organic chemistry , computer science , carbene , embedded system

In the μ‐carbido complex (4) , obtained as shown below, the tin atom is linked to the rhenium atoms via a carbide carbon atom which bonds like a carbyne to the rhenium (TPP stands for tetraphenylporphyrin). An impression of the spatial arrangement of the complexes of type (3) , which are formed at only slightly higher temperatures than (4) , is provided by the adjacent formula.

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