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Preparation of a New Series of Trinuclear Metallophthalocyanines and ‐porphyrins
Author(s) -
Kato Shinzi,
Noda Ippei,
Mizuta Masateru,
Itoh Yuji
Publication year - 1979
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197900821
Subject(s) - rhenium , carbyne , carbide , tetraphenylporphyrin , tin , chemistry , crystallography , atom (system on chip) , porphyrin , inorganic chemistry , photochemistry , catalysis , organic chemistry , computer science , carbene , embedded system
In the μ‐carbido complex (4) , obtained as shown below, the tin atom is linked to the rhenium atoms via a carbide carbon atom which bonds like a carbyne to the rhenium (TPP stands for tetraphenylporphyrin). An impression of the spatial arrangement of the complexes of type (3) , which are formed at only slightly higher temperatures than (4) , is provided by the adjacent formula.