[(triphos)Co(δ‐P 3 )Cr 2 (CO 10 )]: A Trinuclear Heterometal Complex Containing  cyclo ‐Triphosphorus as μ 3 ‐Ligand | Zendy

Midollini Stefano | Zendy; Orlandini Annabella | Zendy; Sacconi Luigi | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

[(triphos)Co(δ‐P 3 )Cr 2 (CO 10 )]: A Trinuclear Heterometal Complex Containing cyclo ‐Triphosphorus as μ 3 ‐Ligand

Author(s) -

Midollini Stefano,

Orlandini Annabella,

Sacconi Luigi

Publication year - 1979

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.197900811

Subject(s) - triphos , chemistry , ligand (biochemistry) , molar ratio , ring (chemistry) , stereochemistry , crystallography , molecule , receptor , organic chemistry , catalysis , biochemistry

The P atoms of the P 3 ring in the complex (triphos)Co(δ‐P 3 ) still possess donor properties. Hence the complex can react with Cr(CO) 6 in the molar ratio 1:1 or 1:2 to give a di‐or trinuclear complex (1) . The original “donor complex” with a CoP 6 skeleton remains almost unchanged on bonding to the Cr(Co) 5 groups.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research