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[(triphos)Co(δ‐P 3 )Cr 2 (CO 10 )]: A Trinuclear Heterometal Complex Containing cyclo ‐Triphosphorus as μ 3 ‐Ligand
Author(s) -
Midollini Stefano,
Orlandini Annabella,
Sacconi Luigi
Publication year - 1979
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197900811
Subject(s) - triphos , chemistry , ligand (biochemistry) , molar ratio , ring (chemistry) , stereochemistry , crystallography , molecule , receptor , organic chemistry , catalysis , biochemistry
The P atoms of the P 3 ring in the complex (triphos)Co(δ‐P 3 ) still possess donor properties. Hence the complex can react with Cr(CO) 6 in the molar ratio 1:1 or 1:2 to give a di‐or trinuclear complex (1) . The original “donor complex” with a CoP 6 skeleton remains almost unchanged on bonding to the Cr(Co) 5 groups.