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Oxidation of Hydrocarbons with Benzyl(triethyl)ammonium Permanganate
Author(s) -
Schmidt H.Jürgen,
Schäfer Hans J.
Publication year - 1979
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197900681
Subject(s) - permanganate , chemistry , ammonium , salt (chemistry) , potassium permanganate , organic chemistry , inorganic chemistry
Oxidation of CH bonds by permanganate in organic solvents becomes possible on use of the salt benzyl(triethyl)ammonium permanganate. Hydrocarbons such as (1) and (2) are oxidized mainly to ketones and tertiary alcohols, repectively, while ethers such as (3) give esters.