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Addition of Water to o ‐Phenylethynyl‐Substituted Triphenylphosphanes
Author(s) -
Winter Werner
Publication year - 1978
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197809472
Subject(s) - stereospecificity , recrystallization (geology) , chemistry , ethanol , medicinal chemistry , stereochemistry , organic chemistry , catalysis , geology , paleontology
The stereospecific hydrogenation of a CC bond and addition of oxygen to phosphorus are effected by straightforward recrystallization of (1) , R, R′ = H and/or CCPh, from commercial grade ethanol. A side product of unusual structure affords further information about the reaction mechanism.