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Structure of the First Open‐Chain Diorganotin Chalcogenide
Author(s) -
Puff Heinrich,
Bongartz Anne,
Sievers Rolf,
Zimmer René
Publication year - 1978
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197809391
Subject(s) - chalcogenide , planar , chain (unit) , crystallography , sulfide , materials science , chemistry , stereochemistry , computer science , physics , organic chemistry , optoelectronics , computer graphics (images) , astronomy
Polymeric diisopropyltin sulfide (1) , a new stable modification of such compounds made up of long planar chains (X‐ray structure analysis), is formed from i Pr 2 SnCl 2 and Na 2 S in DMF. Hitherto only puckered six‐ and planar four‐membered rings were known in this class of compounds.