Premium
trans ‐3,6‐Dioxa‐9‐azatris‐σ‐homobenzene and cis ‐Epoxyepimino‐1,3‐cyclohexadiene
Author(s) -
Francotte Eric,
Merényi Robert,
Viehe Heinz Günter
Publication year - 1978
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197809361
Subject(s) - stereospecificity , adduct , chemistry , primary (astronomy) , medicinal chemistry , stereochemistry , organic chemistry , catalysis , physics , astronomy
A facile entry to oxaazahomobenzene derivatives such as (2) is provided by the reaction of (1) with 1,3‐dienes. Stereospecific addition is followed by rearrangement of the primary adduct.