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1,2,3‐Tri‐ tert ‐butylphosphirane Oxide and Its Thermal Decomposition into ( Z )‐2,2,5,5‐Tetramethyl‐3‐hexene and tert ‐Butylphosphinidene Oxide
Author(s) -
Quast Helmut,
Heuschmann Manfred
Publication year - 1978
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197808671
Subject(s) - oxide , thermal decomposition , derivative (finance) , chemistry , hexene , decomposition , medicinal chemistry , phosphinidene , photochemistry , organic chemistry , catalysis , financial economics , economics , ethylene
The first phosphirane oxide (1) has now been obtained by elimination of HCl from the corresponding open‐chain compound. On warming, compound (1) decomposes to the alkene (2) and the phosphinidene oxide (3) , which could be trapped with a o ‐benzoquinone derivative.