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Heteronuclear Cobalt Clusters by Metal Exchange
Author(s) -
Beurich Harald,
Vahrenkamp Heinrich
Publication year - 1978
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197808631
Subject(s) - heteronuclear molecule , cobalt , oligomer , thermal decomposition , metal , product (mathematics) , chemistry , decomposition , inorganic chemistry , polymer chemistry , organic chemistry , molecule , mathematics , geometry
The directed modification of cobalt‐containing clusters is possible by exchange of Co for other metals. This generalizable synthetic strategy involves attachment of an AsMe 2 M(CO) 3 Cp chain to Co and thermal decomposition of the product with release of an oligomer having the approximate composition [(CO) 3 CoAsMe 2 ] x (1) ; M = Cr, Mo, W.