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Catalytic Carbon‐Carbon Bond Formation with Carbene Intermediates
Author(s) -
HenriciOlivé Gisela,
Olivé Salvador
Publication year - 1978
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197808622
Subject(s) - methylamine , carbene , catalysis , acetonitrile , chemistry , medicinal chemistry , carbon fibers , photochemistry , organic chemistry , materials science , composite number , composite material
The transformation of methylamine into acetonitrile is catalyzed, e. g. by Moon SiO 2 . On admixture of hydrogen (H 2 :CH 3 NH 2 = 12:1) 20–30% of the methylamine are converted into the C 2 product. The reaction proceeds via an intermediate of the type H 2 CM.