Stabilization of a Phosphinic Anhydride R 2 POPR 2  on Gold( I ) and Formation of the Trinuclear Complex (R 2 POAu) 3 —Production of an Octahedral Structural Unit Ag 4 Br       2    2+     by Clamping with R 2 PN(R′)PR 2 | Zendy

Schmidbaur Hubert | Zendy; Aly Aref. A. M. | Zendy; Schubert Ulrich | Zendy

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Stabilization of a Phosphinic Anhydride R 2 POPR 2 on Gold( I ) and Formation of the Trinuclear Complex (R 2 POAu) 3 —Production of an Octahedral Structural Unit Ag 4 Br 2 2+ by Clamping with R 2 PN(R′)PR 2

Author(s) -

Schmidbaur Hubert,

Aly Aref. A. M.,

Schubert Ulrich

Publication year - 1978

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.197808461

Subject(s) - ligand (biochemistry) , octahedron , chemistry , crystallography , stereochemistry , crystal structure , receptor , biochemistry

Tetra‐ tert ‐butyldiphosphoxane, a new complex ligand , has now been stabilized for the first time in the gold compound (2) . Compound (2) was obtained from ClAuCO and t Bu 2 PCl via the complex (1) . There is also something new to report about a related “old” ligand: the 1:2 complex of Ph 2 PNMePPh 2 with AgBr contains a clamped Ag 4 Br 2 octahedron.

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