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Dichlorocarbene Complexes of Iron(II)‐Porphyrins–Crystal and Molecular Structure of Fe(TPP)(CCl 2 )(H 2 O)
Author(s) -
Mansuy Daniel,
Lange Marc,
Chottard J. C.,
Bartoli J. F.,
Chevrier Bernard,
Weiss Raymond
Publication year - 1978
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197807811
Subject(s) - dichlorocarbene , porphyrin , ligand (biochemistry) , chemistry , crystallography , crystal structure , photochemistry , stereochemistry , receptor , biochemistry
The structure of an iron porphyrin with dichlorocarbene as ligand has now been estabished by X‐ray analysis. The complex (1) accordingly contains a planar Fe(TPP)skeleton with H 2 O and CCl 2 as axial ligands. The structural unit (2) is almost linear.