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Enantioselective Synthesis of Homoallyl Alcohols via Chiral Allylboronic Esters
Author(s) -
Herold Thomas,
Hoffmann Reinhard W.
Publication year - 1978
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197807682
Subject(s) - enantioselective synthesis , chemistry , optically active , organic chemistry , boranes , combinatorial chemistry , catalysis , boron
Optically active homoallyl alcohols of type (2) are preparable in good yields by an enantioselective synthesis. endo ‐Phenyl‐ exo,exo ‐glycol, which affords the ester (1) with boranes B(CH 2 CR 2 CH 2 ) 3 , serves as (regenerable) chiral auxiliary compound.