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Decamethyl‐1λ 3 ,4λ 3 ‐diphospha‐2,3,5,6,7‐pentastannabicyclo[2.2.1] heptane, a Bicyclic Compound Rich in Tin
Author(s) -
Mathiasch Bernd,
Dräger Martin
Publication year - 1978
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197807671
Subject(s) - bicyclic molecule , heptane , tin , chemistry , medicinal chemistry , organic chemistry
A “norbornane” whose skeleton contains five tin and two phosphorus atoms is formed on base‐catalyzed reaction of dimethylstannane with white phosphorus (DMF/Et 2 O/295K). The rigid bicyclic skeleton is retained in solution.