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2,3‐Dioxa‐7‐thiabicyclo[2.2.1]heptane: A New Heterobicyclic System Possessing the Thiaozonide Structure
Author(s) -
Adam Waldemar,
Eggelte Henny J.
Publication year - 1978
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197807651
Subject(s) - heptane , materials science , chemistry , organic chemistry
The first thiaozonides of type (1) have now been synthesized and characterized. (1a) , R = Me, and (1b) , R = t Bu, are stable at −20°C but decompose to diketones at room temperature.