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1,3‐Bis(dimethylamino)vinylcarbene
Author(s) -
Gompper Rudolf,
Sobotta Rainer
Publication year - 1978
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197807621
Subject(s) - psychology , philosophy
A nucleophilic vinylcarbene (2) can be obtained from acceptor‐substituted vinamidinium salts (1), A = COPh or CO 2 Et, X=ClO 4 . (2) can be trapped, e.g. as the zwitterion (3) with tetraethyl allenetetracarboxylate.