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Hydrosulfuration‐Thionation of Unsaturated Amides
Author(s) -
Alper Howard,
Currie Janie K.,
Sachdeva Rajeev
Publication year - 1978
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197806892
Subject(s) - aryl , chemistry , transformation (genetics) , medicinal chemistry , organic chemistry , alkyl , biochemistry , gene
N ‐Aryl‐β‐mercaptothioamides (2) are formed by an unexpected reaction of the unsaturated amides (1) with P 4 S 10 /NaHCO 3 . Under these conditions carbonyl compounds are known to undergo transformation into thiocarbonyl compounds