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Synthesis and Structure of the Ylide Complex [(Ph 3 PC 5 H 4 )Co(CO) 2 ] + [Co(CO) 4 ] − · Its Use in the Cyclotrimerization of Alkynes
Author(s) -
Holy Norman L.,
Baenziger Norman C.,
Flynn R. M.
Publication year - 1978
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197806861
Subject(s) - ylide , chemistry , x ray crystallography , crystallography , stereochemistry , physics , diffraction , optics
An ylide complex catalyzing the cyclotrimerization of alkynes is formed on reaction of the ylide (1) with Co 2 (CO) 8 . The complex was characterized by X‐ray structure analysis.