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Elimination of CH 3 from the Radical Cation of Methyl Isobutyrate: Fast CC Cleavage after Rate‐Determining H‐Migration
Author(s) -
Wesdemiotis Chrysostomos,
Schwarz Helmut
Publication year - 1978
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197806781
Subject(s) - cleavage (geology) , chemistry , mass spectrometry , medicinal chemistry , stereochemistry , chromatography , materials science , fracture (geology) , composite material
The behavior of methyl isobutyrate (1) in the mass spectrometer has now been largely elucidated: (1) is the first system in which methyl elimination has been shown to proceed in two steps.