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Evidence for a Dialkoxyalkene Radical Cation in Aqueous Solution
Author(s) -
Behrens Günter,
Bothe Eberhard,
Eibenberger Johann,
Koltzenburg Günther,
SchulteFrohlinde Dietrich
Publication year - 1978
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197806042
Subject(s) - aqueous solution , radical ion , chemistry , spectroscopy , radical , conductivity , photochemistry , hydroxyl radical , radical cyclization , ion , organic chemistry , physics , quantum mechanics
Spontaneous elimination of Cl⊖ from the radical (1) , leading to the radical cation (2) , has now been demonstrated in aqueous solution. The radical character, structure, and charge of (2) were confirmed by ESR spectroscopy and pulse conductivity measurements.