Directed Cooperativity and Site Separation of Mercapto Groups in Synthetic Polymers | Zendy

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Directed Cooperativity and Site Separation of Mercapto Groups in Synthetic Polymers

Author(s) -

Wulff Günter,

Schulze Ilona

Publication year - 1978

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.197805371

Subject(s) - copolymer , divinylbenzene , styrene , cooperativity , polymer , chemistry , sulfur , polymer chemistry , group (periodic table) , organic chemistry , biochemistry

A polymeric model system, sensitive only to the distance between the functional groups , is obtained by copolymerization of (1) with styrene and/or divinylbenzene. After reduction the sulfur is present largely as SH groups which can be reoxidized almost completely to SS bridges. A highly pronounced site separation of SH groups could be accomplished (<5% reoxidation) in comparable experiments with (2) .

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