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Optically Active Polyvinyl Compounds with Chirality in the Main Chain
Author(s) -
Wulff Günter,
Zabrocki Karl,
Hohn Johann
Publication year - 1978
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197805352
Subject(s) - optically active , copolymer , chirality (physics) , polymer , polymer chemistry , methacrylate , side chain , methyl methacrylate , chain (unit) , chemistry , materials science , organic chemistry , physics , chiral symmetry breaking , quantum mechanics , astronomy , nambu–jona lasinio model , quark
Linear polymer chains containing chiral regions are formed on radical copolymerization of p ‐vinylphenylboronic acid, bound to a D‐mannitol template, with methyl methacrylate. After removal of the template, the optically active co‐polymer contains asymmetric triads such as I.