Directed Synthesis of [Mo 3 S 13 ] 2− , an Isolated Cluster Containing Sulfur Atoms in Three Different States of Bonding | Zendy

Müller Achim | Zendy; Sarkar Sabyasachi | Zendy; Bhattacharyya Ram Gopal | Zendy; Pohl Siegfried | Zendy; Dartmann Mechtild | Zendy

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Directed Synthesis of [Mo 3 S 13 ] 2− , an Isolated Cluster Containing Sulfur Atoms in Three Different States of Bonding

Author(s) -

Müller Achim,

Sarkar Sabyasachi,

Bhattacharyya Ram Gopal,

Pohl Siegfried,

Dartmann Mechtild

Publication year - 1978

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.197805351

Subject(s) - bioinorganic chemistry , chemistry , aqueous solution , sulfur , polysulfide , cluster (spacecraft) , inorganic chemistry , transition metal , crystallography , stereochemistry , organic chemistry , catalysis , electrode , electrolyte , programming language , computer science

Transition metal‐suffer clusters , possessing interest as model compounds for bioinorganic chemistry, have previously been prepared mainly by unusual reactions and in frequently low yields. The synthesis of (NH 4 ) 2 [Mo 3 S(S 2 ) 6 ]·½H 2 O has now been accomplished in aqueous solution from MoCl 4 (py) 2 and ammonium polysulfide.

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