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High‐Pressure Carbonylation of Metal‐Coordinated Carbenes and Hydrogenolysis of the Ketene Complexes
Author(s) -
Herrmann Wolfgang A.,
Plank Johann
Publication year - 1978
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197805252
Subject(s) - hydrogenolysis , ketene , carbonylation , chemistry , carbene , metal , catalysis , organic chemistry , carbon monoxide
A model of a step in the Fischer‐Tropsch synthesis has been found in the newly accomplished high‐pressure carbonylation of the carbene complexes (1) to the ketene complexes (2). Hydrogenolysis of (2) is also new.