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Photochemical Reductive trans ‐Elimination from trans ‐Diazidotetracyanoplatinate(IV)
Author(s) -
Vogler Arnd,
Kern Alfred,
Hüttermann Jürgen
Publication year - 1978
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197805241
Subject(s) - reductive elimination , chemistry , radical , photochemistry , one electron reduction , reduction (mathematics) , catalysis , organic chemistry , mathematics , geometry , electrode , electrochemistry
The first light‐induced reductive trans elimination has been observed with the trans ‐configurated Pt IV complex (1) . The primary photochemical step leads, via simultaneous two‐electron reduction avoiding a Pt III intermediate, to two N 3 radicals which afford N 2 and N atoms at low temperature.