Novel Coordination of (Benzoylmethylene)triphenylphosphorane in a Nickel Oligomerization Catalyst | Zendy

Keim Wilhelm | Zendy; Kowaldt Frank H. | Zendy; Goddard Richard | Zendy; Krüger Carl | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Novel Coordination of (Benzoylmethylene)triphenylphosphorane in a Nickel Oligomerization Catalyst

Author(s) -

Keim Wilhelm,

Kowaldt Frank H.,

Goddard Richard,

Krüger Carl

Publication year - 1978

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.197804661

Subject(s) - nickel , ethylene , catalysis , toluene , polymer chemistry , chemistry , polymerization , polyethylene , linear low density polyethylene , monomer , organic chemistry , polymer

The first defined complex for oligo‐ and polymerization of ethylene which requires no co‐catalyst is the crystalline nickel complex (1) . Its structure was established by X‐ray analysis. Dissolved in toluene, compound (1) reacts with ethylene (50 bar) at 50°C giving almost exclusively linear α‐olefins; linear polyethylene is formed under a different set of conditions.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research