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Unusual Reaction of Nickelocene with Bis(diphenylphosphino)maleic Anhydride
Author(s) -
Bensmann Walter,
Fenske Dieter
Publication year - 1978
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197804621
Subject(s) - nickelocene , maleic anhydride , cyclopentadiene , polymer chemistry , chemistry , product (mathematics) , organic chemistry , materials science , catalysis , polymer , mathematics , copolymer , geometry , ferrocene , electrode , electrochemistry
The first insertion of cyclopentadiene into a PC bond has been observed in the reaction of nickelocene with doubly Ph 2 P‐substituted maleic anhydride. The product (X‐ray analysis) belongs to a class of compounds having unusual bonding properties.