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Coordinatively Unsaturated Transition Metal‐Substituted Cyclopropenylium Systems
Author(s) -
Weiss Robert,
Priesner Claus
Publication year - 1978
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197804571
Subject(s) - catalysis , homogeneous , salt (chemistry) , transition metal , metal , homogeneous catalysis , chemistry , electron , photochemistry , organic chemistry , physics , thermodynamics , quantum mechanics
A 14‐electron system and hence possibly a novel catalyst has been found in the Pd‐substituted, coordinatively unsaturated cyclopropenylium salt (1) (and its CF 3 SO 3 −analog). 14‐electron systems play an important role in homogeneous catalysis.
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