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Ring Contraction in the Reaction of Cationic C 5 H 5 Mo(CO) 2 Chelate Complexes with Methyllithium
Author(s) -
Brunner Henri,
Schwägerl Heinrich,
Wachter Joachim,
Reisner George M.,
Bernal Ivan
Publication year - 1978
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197804531
Subject(s) - ring (chemistry) , chelation , cationic polymerization , methyllithium , chemistry , contraction (grammar) , crystallography , medicinal chemistry , inorganic chemistry , polymer chemistry , organic chemistry , medicine
The five‐membered chelate ring in cation (1) surprisingly contracts to a three‐membered ring on reaction with CH 3 Li, yielding the complexes