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Structural Elucidation of Diastereoisomeric 1,3,6‐Trioxacyclooctane Systems by Simultaneous Relaxation and Double Resonance Experiments
Author(s) -
Bock Klaus,
Meyer Bernd,
Thiem Joachim
Publication year - 1978
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197804471
Subject(s) - ring (chemistry) , relaxation (psychology) , chemistry , resonance (particle physics) , nuclear magnetic resonance , stereochemistry , computational chemistry , diastereomer , crystallography , organic chemistry , physics , biology , neuroscience , atomic physics
A novel NMR technique permitted structural elucidation of the two complex sugar derivatives (1) and (2) . Surprisingly, they contain an eight‐membered ring.