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Various Adducts of Isothiocyanates to the λ 5 ‐Phosphazene Group of an Azaphosphole
Author(s) -
Schmidpeter Alfred,
von Criegern Thomas
Publication year - 1978
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197804431
Subject(s) - bicyclic molecule , phosphazene , phosphonium , thiocyanate , chemistry , adduct , ring (chemistry) , group (periodic table) , medicinal chemistry , organic chemistry , polymer
The new 1,3,2λ 5 ‐thiazaphosphetidine ring is present in the bicyclic compound (2) , which is formed from the azaphospole (1) and isothiocyanates. Depending upon the substituents and conditions the bicyclic compound (3) and/or a monocyclic phosphonium thiocyanate is formed alongside or instead of (2) .