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Ternary Rhenium Sulfides with [Re 6 S 8 ]‐Clusters
Author(s) -
Spangenberg Manfred,
Bronger Welf
Publication year - 1978
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197803681
Subject(s) - rhenium , ternary operation , octahedron , crystallography , chemistry , layer (electronics) , chain (unit) , type (biology) , inorganic chemistry , physics , geology , crystal structure , computer science , organic chemistry , quantum mechanics , programming language , paleontology
The first clusters to contain Re 6 units are present in compounds (1) to (3) . The six Re atoms form an octahedron with eight S atoms distributed over the faces. Other ternary sulfides of type A x M y S z have chain or layer structures.