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Preparation and Some Reactions of Dimethyl(trimethylsilylimino)silane, Me 2 SiNSiMe 3
Author(s) -
Wiberg Nils,
Preiner Gerhard
Publication year - 1978
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197803621
Subject(s) - silane , double bond , chemistry , materials science , organic chemistry
Compounds with a SiN double bond are rare, highly reactive, and not isolable. The iminosilane (1) was generated by warming a solution containing (2) to room temperature. (1) dimerizes if not trapped.