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Catalytic Allylation of Phenylhydrazones
Author(s) -
Bersellini Ugo,
Chiusoli Gian Paolo,
Salerno Giuseppe
Publication year - 1978
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197803531
Subject(s) - catalysis , substitution (logic) , solvent , chemistry , nickel , organic chemistry , substitution reaction , metal , combinatorial chemistry , medicinal chemistry , computer science , programming language
Nickel( 0 )‐catalyzed reaction of allyl acetate with phenylhydrazones (1) in THF leads to useful yields of C ‐substituted products (2) . Variation of the ligands in L 4 Ni, the solvent, and/or the metal provides a means of accomplishing N ‐substitution instead of C ‐substitution.