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Demonstration of “Sulfene” Insertion into the Metal‐Hydrogen Bond
Author(s) -
Lorenz IngoPeter
Publication year - 1978
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197802851
Subject(s) - metal , hydrogen bond , chemistry , photochemistry , molecule , organic chemistry
Insertion of H 2 CSO 2 (“sulfene”) into the MH bond has been established by experiments with CpW(CO) 3 D. The mild conditions of this reaction should permit the synthesis of numerous sulfinato‐ S complexes, including thermally unstable species.
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