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Organic Syntheses Using Sheet Silicate Intercalates: Low‐temperature Conversion of Olefins to Secondary Ethers
Author(s) -
Adams John M.,
Ballantine James A.,
Graham Samuel H.,
Laub Richard J.,
Purnell J. Howard,
Reid Paul I.,
Shaman Wafa Y. M.,
Thomas John M.
Publication year - 1978
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197802821
Subject(s) - silicate , intercalation (chemistry) , chemistry , inorganic chemistry , layer (electronics) , chemical engineering , organic chemistry , engineering
Water intercalated in montmorillonites can react with 1‐alkenes (1) to give secondary ethers (2) . Efficient preparations of (2) were hitherto unknown. The cations of the layer silicate must be exchanged, preferably for Cu 2+ , prior to the reaction.