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Molecular Structure of [Mn(CO) 4 NSOF 2 ] 2 — A Dinuclear Transition Metal Complex Containing Difluorooxosulfimidato Bridges
Author(s) -
Buss Bruno,
Altena Dieter,
Mews Rüdiger,
Glemser Oskar
Publication year - 1978
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197802801
Subject(s) - transition metal , crystallography , electron , materials science , chemistry , physics , catalysis , nuclear physics , biochemistry
The bonding in complex (1) can be described in two alternative ways. No decision is yet possible between (1a) (Mn I , NSOF 2 as four‐electron donor) and (1b) (Mn 0 , NSOF 2 as three‐electron donor) on the basis of available experimental data, including X‐ray structure analysis.