[(S 2 ) 2 Mo(S 2 ) 2 Mo(S 2 ) 2 ] 2− , a Novel Complex Containing Only S       2    2−     Ligands and a MoMo Bond | Zendy

Müller Achim | Zendy; Nolte WulfOtto | Zendy; Krebs Bernt | Zendy

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[(S 2 ) 2 Mo(S 2 ) 2 Mo(S 2 ) 2 ] 2− , a Novel Complex Containing Only S 2 2− Ligands and a MoMo Bond

Author(s) -

Müller Achim,

Nolte WulfOtto,

Krebs Bernt

Publication year - 1978

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.197802791

Subject(s) - molybdate , context (archaeology) , aqueous solution , ion , redox , chemistry , electron transfer , polysulfide , inorganic chemistry , crystallography , organic chemistry , electrode , electrolyte , paleontology , biology

Mo‐S compounds occur in redox enzymes whose action involves electron transfer Mo VI ⇌Mo V . In this context, interest attaches to the new complex (1) , which is formed on reduction of molybdate( VI ) by polysulfide ions in aqueous solution. In (1) , Mo has the unusual coordination number 9.

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