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An Arsinidene as a Cubane‐Type Structural Unit: Synthesis and Structure of [(CO) 3 Fe—AsCH 3 ] 4
Author(s) -
Röttinger Erika,
Vahrenkamp Heinrich
Publication year - 1978
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197802731
Subject(s) - cubane , sulfur , crystallography , type (biology) , chemistry , unit (ring theory) , crystal structure , geology , paleontology , organic chemistry , mathematics , mathematics education
The first cubane complex of iron to contain no sulfur has the formula [(CO) 3 FeAsCH 3 ] 4 Its synthesis utilized the thermolability of the AsH bond in complexes: (CO) 4 Fe.CH 3 AsH 2 decomposes slowly at room temperature, and faster on heating, to form the Fe 4 As 4 Cubane.