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Sodium‐23 Nuclear Magnetic Resonance Spectroscopy
Author(s) -
Laszlo Pierre
Publication year - 1978
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197802541
Subject(s) - spectroscopy , nuclear magnetic resonance spectroscopy , chemistry , solvation , two dimensional nuclear magnetic resonance spectroscopy , solvation shell , nuclear magnetic resonance , sodium , chemical shift , fourier transform spectroscopy , analytical chemistry (journal) , chemical physics , ion , infrared spectroscopy , stereochemistry , organic chemistry , physics , quantum mechanics
With the availability of Fourier transform spectrometers, 23 Na‐NMR spectroscopy has become an important tool. It affords direct insight into solvation and ion pairing phenomena, both in organic and in bio‐inorganic systems. Monitoring the chemical shifts and linewidths of 23 Na signals gives access to binding constants, reorientational correlation times and the microdynamics of the sodium coordination shell. The binding of other cations can also be studied by 23 Na‐NMR spectroscopy, in competition experiments.