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Isomerization with Methyl Migration in Trimethyl Phosphite‐Arsenido and ‐Antimonido Complexes of Transition Metals
Author(s) -
Malisch Wolfgang,
Janta Reinhard
Publication year - 1978
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197802112
Subject(s) - isomerization , chemistry , transition metal , atom (system on chip) , medicinal chemistry , stereochemistry , photochemistry , catalysis , organic chemistry , computer science , embedded system
Spontaneous rearrangement of complexes (1) , M = Mo or W, E = As, or M = W, E = Sb, slowly affords complexes (2) even at room temperature. The unusual basic activity of the E atom provides the driving force for this reaction.