Premium
Triazene Transfer with Activated 2‐Tetrazenes
Author(s) -
Stöldt Ernst,
Kreher Richard
Publication year - 1978
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197802031
Subject(s) - triazene , nucleophile , ion , chemistry , coupling (piping) , transfer (computing) , coupling reaction , sequence (biology) , combinatorial chemistry , medicinal chemistry , inorganic chemistry , organic chemistry , materials science , computer science , biochemistry , parallel computing , catalysis , metallurgy
N‐Diazonium ions like (2) generally react in the same way as C ‐diazonium ions by elimination of N 2 . The reaction of 2‐tetrazenium salts (1) with anionic nucleophiles Z ⊖ shown below is new: the N 3 sequence of (2) is retained in the products (3), formally the result of coupling between (2) and Z⊖.