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Intramolecular Cycloaddition of a “PO‐Activated” Acetyleneallene Derivative
Author(s) -
Winter Werner,
Scheller Albert,
Butters Thomas,
Holweger Walter
Publication year - 1978
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197801961
Subject(s) - cycloaddition , intramolecular force , derivative (finance) , chemistry , medicinal chemistry , stereochemistry , business , organic chemistry , catalysis , finance
Formation of the cyclobutaoxaphosphorin (1) is the first example of a spontaneously occurring cycloaddition of a non‐perhalogenated acetylene‐allene component. Compounds of type (1) were previously unknown.