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[4 + 3]‐Cycloadditions of Allenyl Cations
Author(s) -
Mayr Herbert,
Grubmüller Bärbel
Publication year - 1978
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197801301
Subject(s) - cyclopentadiene , propargyl , octane , chemistry , halide , medicinal chemistry , bicyclic molecule , cycloaddition , organic chemistry , catalysis
The first cycloadditions involving allenyl cations (1) [eq. (a)] have now been accomplished with propargyl halides and cyclopentadiene. This reaction provides a convenient entry to the bicyclo[3.2.1]octane series.