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Synthesis and Crystal Structure of a Methylenebis(diphenylphosphane) Complex of Silver Bromide Containing a Trigonal Bipyramidal Ag 3 Br 2 Central Unit
Author(s) -
Aly Aref A. M.,
Neugebauer Dietmar,
Orama Olli,
Schubert Ulrich,
Schmidbaur Hubert
Publication year - 1978
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197801251
Subject(s) - trigonal bipyramidal molecular geometry , bromide , crystallography , metal , ligand (biochemistry) , silver bromide , crystal structure , chemistry , unit (ring theory) , materials science , inorganic chemistry , organic chemistry , mathematics , receptor , silver halide , biochemistry , mathematics education , layer (electronics)
The novel structural unit Ag 3 B 2 +lies at the center of the complex formed from equimolar amounts of AgBr and the dpm ligand. The Ag…Ag distances are just too long for metal‐metal bonding.