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Binuclear Iron Complexes Containing Unsymmetrically Substituted Silanediyl Bridges
Author(s) -
Malisch Wolfgang,
Ries Wolfgang
Publication year - 1978
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197801201
Subject(s) - decarbonylation , dissolution , solid state , chemistry , nuclear magnetic resonance spectroscopy , crystallography , spectroscopy , spectral line , nmr spectra database , stereochemistry , photochemistry , organic chemistry , catalysis , physics , quantum mechanics , astronomy
All three possible stereoisomers are formed on light‐induced decarbonylation of the complex (1) in the solid state and in solution at room temperature (detected by NMR spectroscopy). Spectra recorded immediately after dissolution of the crystalline transformation product reveal only the cis isomers.