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A New Synthetic Entry to Mono‐, Bis‐, and Tris‐(amino)sulfonium Salts
Author(s) -
Kresze Günter,
Rössert Michael
Publication year - 1978
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197800641
Subject(s) - sulfonium , reagent , alkylation , cycloaddition , chemistry , tris , combinatorial chemistry , organic chemistry , salt (chemistry) , catalysis , biochemistry
N ‐Sulfinylimmonium tetrafluoroborates (3) are valuable reagents and certainly not mere inorganic curiosities; they are readily accessible by alkylation of N ‐sulfinylamines (1) . Former syntheses of similar salts were much more involved. The salts (3) are very good cycloaddition partners, and also provide a new entry to aminosulfonium salts of type (4) .
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