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L,L‐3,6‐[Methanothio(2,3‐indolo)methano]piperazine‐2,5‐dione, the Smallest Phallotoxin Model
Author(s) -
Wieland Theodor,
Birr Christian,
Zanotti Giancarlo
Publication year - 1978
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197800541
Subject(s) - thioether , piperazine , dipeptide , stereochemistry , chemistry , organic chemistry , biochemistry , amino acid
The characteristic structural unit of the phallotoxins [ e.g. phalloin (1) ] from the green deathcap toadstool, the bridged cyclic dipeptide (2) , has now been synthesized via the cyclic thioether. Compound (2) is nontoxic.
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