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Selenium Dioxide Insertion into the Iron‐Methyl Bond of η 5 ‐C 5 H 5 Fe(CO) 2 CH 3
Author(s) -
Lorenz IngoPeter
Publication year - 1978
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197800531
Subject(s) - selenium , mass spectrum , carbon dioxide , chemistry , transition metal , metal , analytical chemistry (journal) , crystallography , inorganic chemistry , mass spectrometry , environmental chemistry , organic chemistry , chromatography , catalysis
The first seleninato complex to be obtained by SeO 2 insertion is a brown solid that is stable for several days on exposure to air. It was characterized by its mass, 1 H‐NMR, and IR spectra (seleninato‐ Se type). SO 2 insertions into transition metal‐carbon bonds are known.